Optical fiber for WDM system and manufacturing method thereof

ABSTRACT

An optical fiber having a length of 1 km or more with average transmission loss in a wavelength band of 1383 nm being less than average transmission loss in a wavelength band of 1310 nm, wherein a maximum value of any 1 km section loss in the wavelength band of 1383 nm does not exceed the average transmission loss by 0.03 dB/km or more.

BACKGROUND OF THE INVENTION

1 Field of the Invention

The present invention relates to an optical fiber used for wavelength-division multiplexing (WDM) optical transmission, or more particularly, to a metropolitan-based optical fiber and manufacturing method thereof.

2. Description of the Related Art

Conventionally, a technology for increasing a transmission capacity in optical transmission using an optical fiber has been pursued actively.

A transmission loss of an optical fiber generally reaches a minimum at a wavelength of approximately 1550 nm, and therefore it is desirable to use this wavelength band for optical transmission and a dispersion shift optical fiber (DSF) having a zero dispersion wavelength close to a wavelength of 1550 nm has been developed. This optical fiber allows optical transmission with a transmission capacity of several Gbps in a wavelength band of 1.55 μm.

Furthermore, quite vigorous research and development on wavelength-division multiplexing (WDM) optical transmission is being carried out as the technology for increasing a transmission capacity in recent years. Moreover, many investigations are also being carried on an optical fiber preferably used for WDM optical transmission.

When an optical fiber is used for WDM optical transmission, it is required from the standpoint of preventing a mixture of four light waves that no zero dispersion wavelength should exist in the wavelength band used, and therefore a non-zero dispersion shift optical fiber (NZDSF) with no zero dispersion included in the wavelength band used has been developed. Through the development of this NZDSF, WDM transmission has become feasible in a wavelength range of 1530 to 1565 nm (C band) and a wavelength range of 1565 nm to 1625 nm (L band), which has increased a transmission capacity drastically.

In order to increase the transmission capacity in such a WDM optical transmission system, an attempt is made to provide a wider wavelength bandwidth of signal light.

The invention disclosed in U.S. Pat. No. 6,205,268 maintains substantially the same fiber parameters as those of a standard single mode optical fiber as shown in a loss curve 132 and dispersion curve 131 in FIG. 13, reduces a loss peak (133 in FIG. 13) by OH absorption of 1383 nm, reduces a dispersion value of a wavelength band of 1.4 μm and thereby realizes a CWDM (Coarse Wavelength Division Multiplexing) system in a wide wavelength range of wavelength bands of 1.3 μm, 1.4 μm and 1.5 μm. In this CWDM transmission system, the optical fiber has a zero dispersion wavelength in the vicinity of 1310 nm (dispersion curve 131), and therefore there is a proposal of transmission using the wavelength band of 1.3 μm for analog CATV transmission and the wavelength band of 1.4 μm for transmission at 10 Gbps or above. Furthermore, with the proposal of this new CWDM transmission system, a transmission apparatus indispensable to a DWDM (Dense Wavelength Division Multiplexing) transmission in the wavelength band of 1.4 μm has also been developed in recent years and being put to practical use.

With consideration given to the application of WDM transmission to a metropolitan system, given the fact that an overwhelming majority of transmission paths running today are standard single mode fibers, the proposal of above described U.S. Pat. No. 6,205,268 seems excellent. However, given the fact that an overwhelming majority of transmission apparatuses already put to practical use are also transmission apparatuses for the wavelength band of 1.3 μm, it is desirable to use not only the wavelength band of 1.4 μm but also the wavelength band of 1.3 μm for WDM transmission from the standpoints of cost as well as consistency with the actual system.

On the other hand, as the invention disclosed in U.S. Pat. No. 5,905,838, there is a proposal on an optical fiber which shifts the zero-dispersion wavelength to 1350 to 1450 nm as shown in the dispersion curve 134 in FIG. 13 and sets an absolute value of dispersion of 1310 nm and 1550 nm to 1.0 to 8.0 ps/nm/km to thereby realize WDM transmission using both wavelength bands. However, attempting to realize WDM transmission using both wavelength bands results in an unavoidable reduction of the mode field diameter MFD (or effective core area Aeff) as described in the aforementioned US Patent. The above described US Patent regards 49 μm² as an upper limit of Aeff.

Furthermore, U.S. Pat. No. 6,131,415 sets a cladding/core ratio of a core rod to 2.0 to 7.5 to prevent OH groups in an over cladding from spreading into the core during drawing and realize a low OH fiber. However, it is generally known that an absorption peak by OH groups increases when a hydrogen aging test specified by IEC60793-2-50 (first edition 2002-01) Annex C Section C 3.1 is conducted.

Especially when use in a metropolitan system is considered, the following conditions are further required:

-   (1) Many standard single mode optical fibers are already laid and     consistency with these established optical fibers is important. For     this reason, it is desirable to design that fiber parameters such as     MFD, cladding diameter, specific refractive index difference and     transmission characteristics such as optical transmission loss,     dispersion, cutoff wavelength and mechanical characteristics such as     bending and lateral pressure be the same as those of a standard     single mode fiber. -   (2) Optical fibers are generally formed into a cable and laid in     underground conduits. In the case of a metropolitan system, conduits     are tangled in a complicated manner and it is difficult to lay the     optical fibers in long lengths. For this reason, an average length     of a cable piece is about 1 km. On the other hand, optical fibers     are shipped in piece lengths of 25 to 50 km. Normally, an absorption     loss characteristic of 1383 nm by OH never changes by transformation     into a cable, and therefore uniformity in the longitudinal direction     of the transmission characteristic of an optical fiber is an     important factor to secure the quality of the cable.

In the case of a metropolitan system, multi-core cables such as 1000 cores are put to practical use and rather than transmission loss, it is more important for the optical fiber to have excellent uniformity in the characteristic (transmission loss) of approximately 1 km, small loss in connections between fibers, micro bending loss and resistance to lateral pressures, etc. From such a standpoint, in the optical fiber proposed in above described U.S. Pat. No.5,905,838, uniformity of the characteristic of a short fiber is not always guaranteed and the MFD (Aeff) is as small as approximately 7 μm, and therefore connection loss in a connection with a standard single mode optical fiber having an MFD of approximately 9.2 μm becomes 0.3 dB or above, which is not practical. In this way, attempting to achieve perfect consistency with existing transmission paths results in inconsistency in terms of transmission apparatuses, and on the contrary attempting to achieve perfect consistency with existing transmission apparatuses results in inconsistency in terms of transmission paths. Any attempt to optimize this consistency from both aspects of transmission paths and transmission apparatuses has not been made so far.

SUMMARY OF THE INVENTION

The present invention has been implemented taking into account the uniformity of transmission loss for longitudinal direction (i.e., longitudinal uniformity) in 1383 nm of a short fiber of approximately 1 km long and mainly consistency with existing optical fibers as a metropolitan optical fiber.

The present inventor et al. noticed the longitudinal uniformity in transmission loss at wavelength 1383 nm which is an absorption peak of OH and developed its measuring technology and investigated into the longitudinal uniformity of transmission loss in this wavelength band of 1383 nm, and as a result discovered the following points:

For example, with an optical fiber of 25.2 km long, average transmission loss at wavelength 1383 nm is 0.32 dB/km with substantially no absorption peak of OH, a measurement result of section loss for every 1 km showed that there was a large variation of 0.28 to 0.38 dB/km (see FIG. 3). When longitudinal uniformity of transmission loss of this optical fiber at wavelength 1310 nm and wavelength 1550 nm was measured, with regard to section loss for every 1 km, the variation width from an average transmission loss fell within a range of 0.03 dB/km. For this reason, it has been discovered that while the conventional optical fiber could guarantee transmission loss in a short fiber at wavelength 1310 nm or 1550 nm, it could not necessarily guarantee transmission loss in a short fiber at wavelength 1383 nm.

It has also been discovered that as with an Aeff expansion type NZDSF and a dispersion slope reduction type NZDSF, a longitudinal variation of transmission loss of this wavelength band of 1383 nm tends to increase in size as a profile of the optical fiber becomes more complicated.

One aspect of the present invention is to provide a fiber with a variation in the longitudinal direction of transmission loss of the above described wavelength 1383 nm reduced. The optical fiber according to the present invention is an optical fiber having a length of 1 km or more with an average transmission loss in a wavelength band of 1383 nm being less than an average transmission loss in a wavelength band of 1310 nm, characterized in that a maximum value of section loss of any 1 km at wavelength 1383 nm does not exceed the average transmission loss by 0.03 dB/km or more. The maximum value of any section loss of any 1 km in the wavelength band of 1383 nm preferably does not exceed the average transmission loss by 0.01 dB/km or more.

Furthermore, the optical fiber according to the present invention is characterized in that the cutoff wavelength in a length of 22 m is less than 1380 nm.

Furthermore, the optical fiber according to the present invention is characterized in that the average transmission loss at wavelength 1383 nm after a hydrogen aging test is less than an average transmission loss at wavelength 1310 nm.

According to the optical fiber of the present invention, the average transmission loss at wavelength 1383 nm is less than the average transmission loss at wavelength 1310 nm and the maximum value of any 1 km section loss does not exceed the average transmission loss by 0.03 dB/km or more, and therefore it can be used in a wavelength band of 1.38 μm and transmission loss can be guaranteed even with a short cable.

Furthermore, since the cutoff length at a length of 22 m is shorter than 1380 nm, single mode transmission at wavelength 1383 nm is possible.

Furthermore, since the average transmission loss at wavelength 1383 nm after a hydrogen aging test is less than the average transmission loss at wavelength 1310 nm, stable transmission in a wavelength band of 1.38 μm for a long period of time can be guaranteed.

In the present specification, average transmission loss refers to a value obtained by dividing transmission loss (dB) of one continuous length of an optical fiber (that is, length not including connection parts, for example, one turn length) by the continuous length (km). Furthermore, an arbitrary 1 km section loss refers to transmission loss of arbitrary 1 km in the longitudinal direction. Furthermore, a hydrogen aging test refers to a method specified by IEC60793-2-50 (first edition 2002-01) C 3.1. Here, suppose λy in the present invention is 1383 nm. Furthermore, a cutoff wavelength at a length of 22 m refers to a cable cutoff wavelength λcc defined in ITU-T G.650. Suppose other terms not defined in this text will follow definitions and measuring methods according to ITU-T G.650.

A second aspect of the present invention is to provide an optical fiber which-is preferably applicable to DWDM transmission in a wavelength band of 1.3 μm having consistency with existing transmission paths (standard single mode fiber).

The optical fiber of the present invention is characterized by having an MFD of 8 μm at wavelength 1310 nm, no zero dispersion wavelength in a wavelength range of 1280 to 1324 nm, a dispersion absolute value in the wavelength range of 0.1 to 8.0 ps/nm/km, a dispersion slope of 0.1 ps/nm²/km or less, a cutoff wavelength according to a 22 m method of 1270 nm or less and average transmission loss of 0.4 dB/km or less at wavelength 1310 nm. Here, a wavelength band of 1.3 μm refers to a range of wavelength 1280 nm to 1324 nm.

Since the MFD at 1310 nm is 8 μm or above, it is possible to reduce a connection loss with respect to a standard single mode optical fiber whose MFD is approximately 9.2 μm to 0.1 dB or below and maintain consistency with existing transmission paths.

Furthermore, since there is no zero dispersion wavelength in a wavelength range of 1280 to 1324 nm and a dispersion in the wavelength range is 0.1 to 8.0 ps/nm/km, it is possible to practically ignore waveform distortion due to a nonlinear phenomenon such as a mixture of four light waves, etc. Since the absolute value of the dispersion slope is 0.1 ps/nm²/km or less, the difference in the wavelength dispersion value between signal light beams is reduced and optical transmission which effectively reduces the difference in the amount of waveform distortion by wavelength dispersion between signal light beams becomes feasible.

Since the cutoff wavelength is 1270 nm or less according to the 22 m method, only base mode light in a wavelength band of 1.3 μm can propagate. Since the average transmission loss at wavelength 1310 nm is 0.4 dB/km or less, an optical communication in a wavelength band of 1.3 μm is possible.

Furthermore, when the MFD at 1310 nm is 9.5 μm or less or when the zero dispersion length is 1325 to 1350 nm, the optical fiber of the present invention can be realized by only adding a minimum change to the profile of the standard single mode optical fiber, making it possible to realize an optical fiber with excellent manufacturability.

Furthermore, with the optical fiber of the present invention, when an MFD at 1310 nm is A (μm) and a cutoff wavelength according to the 22m method is B (nm), it is possible to realize the above described characteristic by satisfying a relationship of A×B≦11*1000.

Furthermore, with the optical fiber of the present invention, the average transmission loss at wavelength 1383 nm is less than the average transmission loss at wavelength 1310 nm, and therefore by setting the absolute value of dispersion to 0.1 to 8.0 ps/nm/km and setting the dispersion slope to 0.1 ps/nm²/km or less, it is possible to utilize a wavelength band of 1.4 μm in a future expansion of the wavelength range, which is therefore preferable.

Since an increase in average transmission loss at wavelength 1383 nm from before to after a hydrogen aging test is 0.04 dB/km or less, it is possible to provide an optical fiber with excellent long-term reliability accompanied by hydrogen resistance.

A third aspect of the present invention is intended to provide a fiber which has only a small increase of an absorption peak by OH groups at 1383 nm even if a hydrogen aging test is conducted, that is, a fiber with excellent hydrogen resistance and consistent with existing optical fibers as a metropolitan fiber. It is especially intended to provide a method of manufacturing an optical fiber preferably applicable to a WDM transmission in a C band at low costs.

In order to attain the above described objects, the present invention provides a method of manufacturing an optical fiber having a mode field diameter of 8.0 to 11.0 μm at wavelength 1310 nm, average transmission loss at wavelength 1383 nm being less than average transmission loss at wavelength 1310 nm and dispersion of +2 to +8 ps/nm/km at wavelength 1383 nm, characterized in that an optical fiber base material is drawn, coated and the optical fiber strand obtained is subjected to exposure in a vapor phase atmosphere containing a deuterium gas.

In the optical fiber provided with the above described characteristics, those characteristics are used for the following reasons:

-   (1) First, the MFD at wavelength 1310 nm is designed to be 8.0 to     11.0 μm and this is intended to secure consistency when connected to     an existing standard single mode optical fiber. -   (2) The average transmission loss at wavelength 1383 nm is designed     to be less than the average transmission loss at wavelength 1310 nm.     Thus, an increase in transmission loss at wavelength 1383 nm is     suppressed.

This is realized by applying a process which will be described later and thereby suppressing an increase in absorption loss by OH groups at wavelength 1383 nm.

-   (3) Dispersion in the wavelength range of wavelength 1383 nm is     designed to be +2 to +8 ps/nm/km. The optical fiber is preferably     designed to have dispersion of +4 to +7 ps/nm/km at wavelength 1383     nm.

This can suppress influences of a mixture of four light waves and minimize influences of accumulated dispersion when an optical transmission path is constructed.

As long as the above described characteristics are satisfied for the optical fiber manufactured according to the present invention, the shape of a refractive index distribution profile is subject to no restrictions. For example, the refractive index distribution profile applied to a low loss optical fiber shown in FIG. 1 can be used.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a refractive index profile of an optical fiber in an embodiment according to a first aspect of the present invention;

FIG. 2 illustrates a refractive index profile of multilayer cores of an optical fiber in another embodiment according to the first aspect of the present invention;

FIG. 3 illustrates a section loss variation for every 1 km of transmission loss at wavelength 1383 nm in a conventional optical fiber;

FIG. 4 illustrates a refractive index profile of an optical fiber in an embodiment according to a second aspect of the present invention;

FIG. 5 illustrates a refractive index profile of an optical fiber in another embodiment according to the second aspect of the present invention;

FIG. 6 illustrates a refractive index profile of an optical fiber in an embodiment according to a third aspect of the present invention;

FIG. 7 is an example of a transmission loss spectrum of an optical fiber with drawing and with an extremely small amount of OH group;

FIG. 8 is a is an example of a transmission loss spectrum when D2 processing is applied to an optical fiber;

FIG. 9 is a graph showing a relationship between a transmission loss variation and D2 processing time after D2 processing is started;

FIG. 10 illustrates a transmission loss spectrum of an optical fiber before D2 processing;.

FIG. 11 illustrates a transmission loss spectrum of an optical fiber after D2 processing;

FIG. 12 is a graph showing a relationship between a transmission loss difference at wavelength 1420 nm from before to after D2 processing and elapsed time after the D2 processing is started; and

FIG. 13 illustrates a dispersion characteristic and transmission loss characteristic of a conventional optical fiber.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

With reference now to the attached drawings, a first aspect of an optical fiber of the present invention that reduces a transmission loss variation at wavelength 1383 nm and a method of manufacturing thereof will be explained below. FIG. 1 illustrates a refractive index profile of an optical fiber according to the present invention. As a result of investigations into the above described problem of the longitudinal variation of transmission loss at wavelength 1383 nm, the present inventor et al. have discovered that micro variations in the core diameter and the amount of core eccentricity in the longitudinal direction in the stage of the base material of the optical fiber were the causes for the problem. OH groups in the over cladding spread toward the core during drawing and the area close to the over cladding has a higher concentration of OH group. The area where light propagates up to the vicinity of the over cladding with a higher concentration of OH group extends more in an area where the mode field diameter is large than an area where the mode field diameter is small, and therefore the transmission loss at wavelength 1383 nm is liable to increase. Thus, a longitudinal variation of transmission loss at wavelength 1383 nm occurs according to the variation of the mode field diameter.

As described in U.S. Pat. No. 6,131,415, it is disclosed that increasing the cladding/core ratio in a core rod is effective in reducing an average transmission loss at wavelength 1383 nm. However, increasing the cladding/core ratio in the core rod causes a micro variation of the cladding/core ratio to lead to an increase of the MFD or the length of a variation in the amount of mode field eccentricity. To improve these contradictory characteristics, the following changes have been made in the design of a standard single mode optical fiber.

-   1) Using a VAD method, the cladding/core ratio when the core was     manufactured was set to 2 or below. This managed to suppress     influences of the variation in the cladding/core ratio on the     longitudinal direction to 1 km or less. -   2) In the elongation step, etc., an elongation was made using an     electric furnace without using any oxy-hydrogen flame burner.     Avoiding the use of the oxy-hydrogen flame burner which may cause OH     allowed the concentration of OH group of the entire glass to be     reduced to 1 ppm or below. -   3) As shown in FIG. 1, an range of a second cladding 13 obtained by     glassifying soot of a small bulk density was placed at the midpoint     position between the core rod (core 11 and first cladding 12) and     the outermost third cladding 14. The ratio of the core 11 to the     second cladding 13 was set to 6 to 8. The bulk density of the range     of the second cladding 13 in the soot stage is preferably 0.3 g/cm³     or less. This also allowed the concentration of OH group of the     second cladding 13 to be reduced to 1 ppm or below.

The optical fiber base material obtained in this way was drawn into an optical fiber and the characteristic thereof was checked. The following result was obtained, which indicates that the optical fiber is also applicable to a short cable.

Transmission loss at 1310 nm: 0.34 dB/km

Transmission loss at 1550 nm: 0.20 dB/km

Transmission loss at 1383 nm: 0.31 dB/km

Maximum value of 1 km section loss:

-   -   at 1310 nm: 0.36 dB/km     -   at 1550 nm: 0.21 dB/km     -   at 1383 nm: 0.32 dB/km

MFD:

-   -   at 1310 nm: 9.2 μm     -   at 1550 nm: 10.4 μm     -   at 1383 nm: 9.6 μm

This technique was applied to the profile in FIG. 2 and an effective sectional area (Aeff) expansion type NZDSF and a dispersion slope reduction type NZDSF were created as prototypes. That is, the refractive index profile 21 shown in FIG. 2 is a refractive index profile with multilayer cores corresponding to the core 11 shown in FIG. 1. Even in such a case with a multilayer core, the result showed that by providing the second cladding 13 shown in FIG. 1, the maximum value of any 1 km section loss at wavelength 1383 nm would never exceed the average transmission loss by 0.03 dB/km or more.

According to the optical fiber of the present invention, the average transmission loss at wavelength 1383 nm is less than the average transmission loss at wavelength 1310 nm and the maximum value of any 1 km section loss does not exceed the average transmission loss by 0.03 dB/km or more, and therefore the optical fiber can be used at wavelength 1383 nm and transmission loss can be guaranteed even in the case of a short cable. Furthermore, since the average transmission loss at wavelength 1383 nm after a hydrogen aging test is less than the average transmission loss at wavelength 1310 nm, it is possible to guarantee a stable transmission for a long period of time in the vicinity of approximately 1380 nm.

Then, for the consistency of the present invention with existing fibers, an example of the optical fiber with a side with an MFD of 8 μm or more at 1310 nm will be explained with reference to FIG. 4 and FIG. 5.

The optical fiber according to the present invention is preferably applicable to a case where the MFD at 1310 nm is 9.5 μm or less or where the zero dispersion length is 1325 to 1350 μm. The above described characteristic can be realized by satisfying a relationship of A×B≦11*1000 when the MFD at wavelength 1310 nm is A (μm) and the cutoff wavelength according to the 22 m method is B (nm).

Furthermore, with the optical fiber according to the present invention, it is preferable that the average transmission loss at wavelength 1383 nm be less than the average transmission loss at wavelength 1310 nm and the absolute value of dispersion be 0.1 to 8.0 ps/nm/km and the dispersion slope be 0.1 ps/nm²/km or below.

By setting an increase in transmission loss at wavelength 1383 nm from before to after the hydrogen aging test to 0.04 dB/km or below, the present invention can provide an optical fiber with excellent long-term reliability, which is therefore preferable.

The optical fiber according to this embodiment comprises a core area having a refractive index of n1 centered on the optical axis and a cladding area having a refractive index of n2 around the core area. The relationship between those refractive indices is n1>n2. Such an optical fiber can be realized using silica as the base and adding, for example, Ge element to the core area.

For the optical fiber, the soot produced by a VAD method was glassified through dehydration, sintering to obtain a preform, then drawn and coated with two UV cure resin layers to obtain an optical fiber strand of 250 μm in outer diameter. Then, the optical fiber was left standing in a D2 gas atmosphere at a normal temperature and under a normal pressure for approximately 2 hours and checked for the various characteristics shown below.

FIRST EXAMPLE

The optical fiber according to First Example has the refractive index profile made up of a step type core refractive index 41 and a cladding refractive index 42 shown in FIG. 4, wherein the MFD at wavelength 1310 nm is 8.5 μm, the zero dispersion wavelength is 1326 nm, the dispersion slope in a wavelength range of 1280 nm to 1324 nm is 0.08 ps/nm²/km, the absolute value of the dispersion value in the wavelength range is 0.4 to 3.4 ps/nm/km and the cutoff wavelength is 1250 nm. Therefore, A×B (product of MFD and cutoff wavelength) is 10600. The average transmission loss at wavelength 1310 nm was 0.34 dB/km and the average transmission loss at wavelength 1383 nm was 0.29 dB/km. Furthermore, when a hydrogen aging test was conducted on this fiber, the increase in transmission loss at wavelength 1383 nm from before to after the test was 0.00 dB/km.

SECOND EXAMPLE

The optical fiber of Second Example has the refractive index profile shown in FIG. 4, wherein the MFD at wavelength 1310 nm is 8.1 μm, the zero dispersion wavelength is 1340 nm, the dispersion slope in a wavelength band of 1.3 μm is 0.08 ps/nm²/km, the absolute value of the dispersion value in the wavelength band of 1.3 μm is 1.6 to 5.2 ps/nm/km and the cutoff wavelength is 1100 nm. Therefore, A×B (product of MFD and cutoff wavelength) is 8900. The average transmission loss at wavelength 1310 nm was 0.34 dB/km and the average transmission loss at wavelength 1383 nm was 0.29 dB/km. Furthermore, when a hydrogen aging test was conducted on this fiber, the increase in transmission loss at wavelength 1383 nm from before to after the test was 0.00 dB/km.

THIRD EXAMPLE

The refractive index profile of the optical fiber according to the present invention is not limited to the one shown in FIG. 4, but, for example, the one shown in FIG. 5 is also acceptable. This is a profile having a first core refractive index 51 with a peak at the center, a refractive index which is greater than a cladding refractive index 54 by Δ1, a second core refractive index 52 which is smaller by Δ2 and a third core refractive index 53 which is greater by Δ3.

The fiber of the present invention can maintain consistency with existing transmission paths and provides a WDM optical fiber which suppresses generation of a mixture of four light waves in a wavelength band of 1.3 μm.

Furthermore, when the MFD in a wavelength 1310 nm is 9.5 μm or below or when the zero dispersion wavelength is 1325 to 1350 nm, the optical fiber of the present invention can realize an optical fiber with excellent manufacturability, which is therefore preferable.

Furthermore, having the average transmission loss at wavelength 1383 nm being less than the average transmission loss at wavelength 1310 nm, the absolute value of the dispersion of 0.1 to 8.0 ps/nm/km and the dispersion slope of 0. 1 ps/nm²/km or below, the optical fiber of the present invention can thereby utilize a wavelength band of 1.4 μm when the wavelength range used is expanded in the future, which is therefore preferable.

When the increase in average transmission loss at wavelength 1383 nm from before to after a hydrogen aging test is 0.04 dB/km or below, the present invention can provide an optical fiber with excellent long-term reliability, which is further preferable.

An example of implementation of a method of manufacturing a metropolitan optical fiber with excellent hydrogen resistance according to the third aspect of the present invention is as follows.

First, an optical fiber base material is manufactured using a VAD method as in the case of the conventional one. Then, the optical fiber base material is drawn and an optical fiber having a predetermined wire diameter is manufactured and then the optical fiber is coated to be transformed into an optical fiber strand. Then, this optical fiber strand is processed to improve hydrogen resistance. More specifically, this optical fiber strand is accommodated in a processing apparatus and the inside of the apparatus is set in an atmosphere including a deuterium (D2) gas at a normal temperature and under a normal pressure and left standing for a predetermined time.

The deuterium component is charged into the optical fiber body of the optical fiber strand, infiltrates into defects in the optical fiber body and forms bonding. As a result, when the processed optical fiber strand is subjected to a hydrogen aging test, hydrogen that has infiltrated into the optical fiber body cannot couple with the above described defects which are already inactivated, and therefore no increase of any specific absorption peak occurs. That is, hydrogen resistance is improved.

It is preferable to use 10 to 40° C. as the normal temperature and 86 to 106 kPa as the normal pressure during the above described exposure processing. The processing time is changed according to the length of the optical fiber strand to be processed and carrying out processing for 24 hours at longest is enough.

By carrying out such processing, the present invention can provide an optical fiber having the above described characteristics, wherein the amount of increase in transmission loss at wavelength 1383 nm after a hydrogen aging test is 0.04 dB/km or below and further 0.01 dB/km or below.

A refractive index distribution profile of the optical fiber manufactured in this way is shown in FIG. 6 and is of a step type with a core 61 having a higher refractive index than a cladding 62.

This optical fiber strand of approximately 3 km long is placed in the processing apparatus, the inside of the apparatus is set in a substantially 100% deuterium atmosphere at a temperature of 23° C. and under a pressure of 100 kPa and left in that condition for approximately 3 hours.

The optical fiber strand after the processing was subjected to a hydrogen aging test specified by IEC60793-2-50 (first edition 2002-01) Annex C Section C 3.1 and the average transmission loss at wavelength 1383 nm was measured using the method specified by ITU-TG.650. This result is shown together with the measurement result before the test in Table 1. The average transmission loss at wavelength 1310 nm was also measured.

The MFD at wavelength 1310 nm and the dispersion value at wavelength 1383 nm were measured and their results are also shown in Table 1. For comparison, similar measurements are also performed on the optical fiber strand without deuterium exposure processing and the results are shown together as a comparative example. TABLE 1 Transmission loss at wavelength of 1383 nm (dB/km) Refractive Dispersion Transmission loss Before After index distribution value MFD at wavelength of hydrogen hydrogen profile (ps/nm/km) (μm) 1310 nm (dB/km) aging test aging test Example 1 5.8 9.26 0.33 0.31 0.31 Example 2 4.5 9.38 0.32 0.29 0.29 Comparative 5.1 9.14 0.33 0.29 0.39 Example

As is apparent from Table 1, in comparison with the comparative example with no deuterium processing, the optical fiber manufactured by the method of the present invention has no increase in average transmission loss at wavelength 1383 nm from before to after the hydrogen aging test.

As is clear from the above explanation, the present invention can improve hydrogen resistance not in the middle of the manufacture of the optical fiber but in a state of the optical fiber strand which can already be actually used. Therefore, it is possible to manufacture an optical fiber with an increase in transmission loss at wavelength 1383 nm suppressed to 0.04 dB/km or below, having excellent hydrogen resistance and transmission loss which is stable for a long period of time.

Then, this optical fiber is designed in such a way that the MFD at wavelength 1310 nm is 8.0 to 11.0 μm, average transmission loss at wavelength 1383 nm is less than average transmission loss at wavelength 1310 nm and dispersion at wavelength 1383 nm becomes +2 to +8 ps/nm/km, and therefore consistency with existing standard single mode optical fibers is also guaranteed and is useful for construction of an optical network. There is an expectation for its utility as the light ray path used in a C band WDM transmission system.

Another problem is that there are some structural defects in an optical fiber after drawing. When this optical fiber is actually used, H₂ generated from the coating of the optical fiber may be spread within the optical fiber, cross-react with the structural defects and generate OH groups.

Therefore, even if no OH group existed when the fiber was manufactured, new OH groups may be generated when the fiber is actually used, causing absorption loss in the optical fiber.

Such a problem with absorption loss by the OH groups and H₂ causes an increase in transmission loss when a long transmission path is constructed using optical fibers, and this is the problem that must be solved without fail.

Furthermore, Japanese Patent Publication No. 4-4988 proposes an optical fiber which has moved the light absorption wavelength toward the longer wavelength side than the wavelength band of 1550 nm by substituting residual OH groups in glass by OD groups (D: deuterium). However, the actual problem is that this method causes the residual OH groups to be substituted by the OD groups, which requires processing for a long time at a high temperature, which is not economical and lacks in practicality.

Furthermore, Japanese Patent Application Laid-Open No. 2000-187733 discloses the following method. This is the method that exposes the optical fiber after drawing to a deuterium (D2) atmosphere prior to its actual use and generates OD groups in the structural defects after drawing in a stage prior to generating OH groups with H₂ in the-operating environment. This prevents cross-reaction between the structural defects of the optical fiber and H₂ in the operating environment and prevents new OH groups from being generated.

The development of this prior art allows optical absorption based on H₂ molecules at wavelength 1240 nm and optical absorption based on OH groups at wavelength 1400 nm to be controlled. However, when the optical fiber after drawing is exposed to a deuterium (D2) atmosphere, D2 molecules are spread into glass. Then, absorption loss by the OD groups generated in the cross-reaction with the structural defects in glass occurs on the longer wavelength side than the wavelength band of 1550 nm. At the same time, absorption loss by free D2 molecules themselves occurs in the vicinity of wavelength 1420 nm. Then, though absorption loss by these D2 molecules is small, it will increase apparent transmission loss of the optical fiber.

This will cause the following problems. First, as described above, absorption of the OH groups occurs in a wavelength band of 1400 nm. Therefore, the absorption of the OH groups in the wavelength band of 1400 nm should have already been solved through deuterium processing (hereinafter referred to as “D2 processing”), but an increase in the above described transmission loss is observed in the optical fiber after D2 processing, which may cause the observer to judge that OH groups exist in this optical fiber.

As a result, further D2 processing may be continued using extremely expensive D2. This means that OD groups are actually generated in all structural defects due to D2 processing, that is, the above described phenomenon of an increase in transmission loss based on the absorption loss of D2 molecules is misidentified as being based on OH group absorption due to the presence of the OH groups. This is because no standard for defining the appropriate time point at which D2 processing ends has been established yet.

Therefore, a method of manufacturing an optical fiber should be provided which will solve the above described problem and define an appropriate time point at which D2 processing ends based on new knowledge about the behavior of light absorption due to D2 molecules after D2 processing.

The present invention provides a method of manufacturing an optical fiber including a step of carrying out deuterium processing on an optical fiber after drawing, characterized by having a time point at which the difference between the difference between the average transmission loss at wavelength 1383 nm and the average transmission loss at wavelength 1420 nm of the optical fiber before deuterium processing, and the difference between the average transmission loss at wavelength 1383 nm and the average transmission loss at wavelength 1420 nm of the optical fiber after deuterium processing is 0.01 dB/km or more.

More specifically, the present invention provides a method of manufacturing an optical fiber which provides a time interval of 48 hours or more from the time point at which the deuterium processing is started to the time point at which the transmission loss is measured for the optical fiber at 25° C.

In the following explanations, the “wavelength band of 1400 nm” means an arbitrary point at wavelength 1335 to 1435 nm and the “wavelength band of 1550 nm” means an arbitrary point at wavelength 1500 to 1600 nm. Furthermore, D2 processing refers to exposure of the optical fiber to a D2 atmosphere which has a higher concentration than that in the atmosphere.

One example of an optical fiber transmission loss spectral diagram obtained by applying drawing to the optical fiber base material manufactured using a normal method is shown in FIG. 7.

In this spectral diagram, the peak appearing in the vicinity of wavelength 1383 nm is transmission loss caused by OH groups and this optical fiber is ready for optical transmission in both the wavelength band of 1400 nm and wavelength band of 1550 nm.

Then, the above described optical fiber is subjected to D2 processing and a transmission loss spectral diagram of the processed optical fiber 72 hours after the D2 processing is started is shown in FIG. 8.

The D2 processing is carried out in such a way that the optical fiber to be processed is housed in a sealed container, N₂, etc., containing D2 of a predetermined concentration is sealed in the container and left as is for a desired time.

As is apparent from FIG. 8, new transmission loss (A) appears in the vicinity of wavelength 1420 nm and other new transmission loss (B) also appears in the vicinity of wave length 1500 nm. The latter is based on the generation of absorption loss by OD groups made up of deuterium atoms D coupled with structural defects in the optical fiber before the D2 processing.

Then, the former is an increase of loss caused by light absorption of the D2 molecules themselves spread in the optical fiber.

Thus, the present inventor et al. measured transmission loss (A) over time at wavelength 1420 nm after the D2 processing started, subtracted transmission loss before the D2 processing from the measured values at various time points and examined the relationship between the amount of variation of transmission loss and D2 processing time. The result is shown in FIG. 9.

As is apparent from FIG. 9, the moment the D2. processing is started, transmission loss increases drastically compared to the value before the D2 processing and reaches a maximum when a processing time of 72 hours has elapsed. From then on the transmission loss (A) decreases gradually.

From this new knowledge, the following points can be considered:

-   (1) The moment the D2 processing is started, D2 molecules start to     spread in the optical fiber until they are saturated. For that     reason, the absorption loss by D2 molecules increases compared to     the state before the D2 processing and the transmission loss of the     optical fiber increases drastically. -   (2) Then, from the saturation state on, some portions of D2     cross-react with structural defects and are fixed as OD groups     sequentially, and therefore the amount of D2 molecules in the     optical fiber decreases sequentially and the absorption loss also     decreases accordingly. On the contrary, the transmission loss     increases with the absorption loss of OD groups. -   (3) Then, after all structural defects have become OD groups, the     residual D2 molecules have no counterparts of reaction and therefore     they escape out of the optical fiber. This escaping behavior is     considered to have a balancing relationship with the spreading     behavior from outside to inside of the optical fiber. -   (4) Therefore, when a certain time elapses from the D2 processing,     at a certain time point at which the transmission loss of the     D2-processed optical fiber turns to a decrease, the structural     defects have already completed the coupling with the OD groups, and     therefore that time point can be regarded as the time point at which     the D2 processing has ended.

An improved method of manufacturing an optical fiber has been developed based on the above described new knowledge and considerations.

More specifically, from before to after the D2processing, the average transmission loss (suppose a dB/km) at wavelength 1383 nm is measured and at the same time the average transmission loss (suppose b dB/km) at wavelength 1420 nm is measured and the time point at which the difference from before to after the D2 processing of a-b falls below 0.004 dB/km is regarded as the time point at which the D2 processing ends.

Here, the wavelength 1383 nm is selected because this wavelength is the wavelength indicating an absorption peak specific to OH groups and the loss is hardly changed due to influences of the D2 processing. The wavelength 1420 nm is selected because it is possible to check from this variation in wavelength loss whether D2 molecules have reached the core or not. Furthermore, the (a-b) value is set to 0.01 dB/km or below because it is necessary to confirm that D2 have securely entered the core.

More specifically, by leaving the fiber at temperature 25° C. for 48 hours or more after the D2 processing is started, the above (a-b) value can be set to 0.01 dB/km or more.

The optical fiber satisfying the above described condition when the fiber length is 10 km or more is an optical fiber whose cutoff wavelength in a length of 22 m is 1300 nm or below.

When the average transmission loss of the optical fiber after the D2 processing is measured, it is preferable to leave the optical fiber in an atmosphere whose concentration is lower than the maximum concentration of D2 during the D2 processing for 300 hours or more. This is because the balancing relationship between the escaping and spreading of the aforementioned D2 molecules is collapsed toward the escape side and D2 molecules escape to the outside, and the absorption loss caused by free D2 molecules in the optical fiber practically disappears.

As is apparent from the above described explanation, the present invention allows the time point at which the D2 processing ends to be appropriately determined. Then, OH group absorption is also suppressed in a wide wavelength range of 1400 to 1550 nm and it is possible to manufacture an optical fiber usable for CWDM transmission.

Furthermore, when the average transmission loss of the optical fiber after the D2 processing is measured, it is also possible to discern whether the average transmission loss is based on the absorption loss of D2 molecules or other factors such as bending loss, etc.

Another problem is that even when an optical fiber is manufactured using high purity silica, only OH groups of on the order of 0.1 ppm normally exist in the optical fiber but there is a variation over time in the generation of OH groups.

That is, after drawing, even if the optical fiber with fewer OH groups is laid and actually used, it is exposed to surrounding hydrogen at an ambient temperature, the hydrogen spreads into the optical fiber and forms OH groups and transmission loss at wavelength 1300 nm to 1600 nm, and wavelength 1380 to 1600 nm in particular is known to increase overtime. The variation over time of transmission loss caused by the presence of this hydrogen is normally called “hydrogen secular variation loss.”

Influences of such hydrogen spread is even observed through the cladding when optical fibers are bundled as a communication cable. This hydrogen spreading is also already observed even when the fiber is exposed to an atmosphere of trace hydrogen on the order of 0.01% at a normal temperature and loss of, for example, 0.02 dB/km to 0.12 dB/km is observed at wavelength 1383 nm.

On the other hand, hydrogen is generated based on a corrosion phenomenon due to heterogeneous metal which exists in the optical cable and ambient humidity or is believed to be generated by heated silicon resin which makes up the coating. In the case of the optical fiber laid in the seawater or in the atmosphere, there is a problem that it has particularly large hydrogen secular variation loss.

With respect to these problems, prior to the actual use of an optical fiber, there is a proposal of D2processing whereby prior to its actual use, the optical fiber is exposed to a deuterium (D2) atmosphere and then left standing in the atmosphere (e.g., see Japanese Patent Application Laid-Open No. 2002-148450).

This method is intended to eliminate causes for generation of OH groups in actual use by letting D2 react with structural defects and OH groups which exist in the optical fiber after drawing and then leaving them standing for a predetermined time and thereby prevent transmission loss based on the generation of OH groups from increasing.

However, in the case of the D2 processing described in the above described patent document 1, the problem is that the D2 processing time is very long and the time during which D2 molecules which have been spread into the optical fiber through D2 processing and remain without reacting with OH groups are left standing so as to escape out of the optical fiber is also very long. Thus, the above described prior art results in low production efficiency in actual industrial production and cannot be necessarily considered as a satisfactory method in practicality.

For this reason, there is a demand for provision of a method of manufacturing an optical fiber which solves the above described problems in the conventional D2 processing, carries out D2 processing quickly and efficiently and secures long-term stability of the transmission characteristic.

In order to attain the above described object, the present invention provides a method of manufacturing an optical fiber characterized in that an optical fiber immediately after being drawn and wound around a bobbin is exposed to a gas atmosphere containing a deuterium gas and then rewound around another bobbin while applying tensile tension thereto before the deuterium gas in the optical fiber is fully drained.

In that case, the tensile tension is preferably equivalent to 0.5 to 2% in terms of an elongation value of the optical fiber and when the optical fiber is rewound, the optical fiber is preferably cut and split to a desired length in the longitudinal direction.

In an example of implementation of the method of the present invention, an optical fiber base material is drawn using a normal method, the coated optical fiber is wound around a bobbin and immediately subjected to D2 processing. More specifically, this example is implemented in such a way that the bobbin immediately after the optical fiber is wound is housed in a sealed container, a gas containing D2 is sealed into the container and left as is for a predetermined time.

As the ambient gas, for example, a mixed gas of air or inert gas (He, Ar, N₂, etc.) and D2 is used and in that case, it is preferably a gas containing 0.01 to 100% D2. The mixed gas containing almost 100% D2 can suppress an increase in transmission loss even through short-time processing and is preferable in terms of processing efficiency.

The processing time less than 1 hour cannot allow the effect of the D2 processing to be demonstrated fully and the effect reaches saturation even after 10 hours and reduces the production efficiency needlessly, and therefore the processing time is preferably 1 to 10 hours. It is more preferably around 2 hours.

When the temperature during the D2 processing is too low, the reaction of D2 processing becomes slower, whereas when the temperature is too high, the processing time may be shortened but there is a danger that the coating may be deteriorated, and therefore the temperature during the processing is preferably controlled to within the range of 25±3° C.

After the D2 processing, the processed optical fiber is rewound around another bobbin immediately. At this time, tensile tension should be applied to the optical fiber.

That is, a great feature of the present invention is that it is possible to omit the step of leaving the fiber as it is for a long time after D2 processing for draining the gas of free D2 molecules as in the case of the conventional art.

This rewinding can be executed not only in an air-conditioned atmosphere but also in a nitrogen atmosphere.

Then, when tensile tension is applied to the optical fiber, a load is applied to the coating and the temperature of the optical fiber core (glass) increases a little by flexion and friction energy of the coating. Furthermore, tensile tension is also applied to the optical fiber core (glass) and since the D2 concentration on the surface of the optical fiber core is zero or very close to zero, the residual D2 molecules inside the core is likely to escape to the outside, which shortens the time required for gas draining.

The tensile tension applied at this time is set to a level such that an elongation of the optical fiber is 0.5 to 2.5%. This is because in the case of the application of tension corresponding to an elongation less than 0.5%, the above described effect cannot be obtained, while in the case of the application of tension corresponding to an elongation greater than 2.5%, there is a danger that the coating may be damaged. Furthermore, during this rewinding, cutting the optical fiber into a desired length eliminates the need for providing an additional cutting/splitting step and is therefore efficient.

An optical fiber base material was drawn and an optical fiber was manufactured using a conventional method and this was wound around a bobbin. One example of a transmission loss spectral diagram of this optical fiber is shown in FIG. 10. In FIG. 10, a peak A0 appearing in the vicinity of wavelength 1380 nm is a transmission loss caused by OH groups.

Then, the bobbin was placed in a sealed container and a gas of D2 100% and N2 0% was sealed therein and left standing at a temperature of 25° C. for two hours and D2 processing was performed. After the D2processing under the above described condition, the optical fiber was left standing for 72 hours and its transmission loss was measured. The result is shown in FIG. 11. As is apparent from the transmission loss spectral diagram in FIG. 11, a new peak A1 appears in the vicinity of wavelength 1420 nm and a new broad peak A2 also appears in the vicinity of wavelength 1500 nm. The former A1 is an increase of loss caused by absorption by D2 molecules themselves spread in the optical fiber and the latter A2 is based on the absorption loss due to OD groups formed by coupling structural defects and deuterium atoms D before D2 processing.

Then, the optical fiber around the bobbin was rewound a round another bobbin in the atmosphere. At this time, tensile tension was applied to the optical fiber so that its elongation reached 1.1% and cut and separated every 25.26 km. Then, transmission loss at wavelength 1420 nm after D2 processing was started was measured over time, the transmission loss before the D2 processing (value at 1420 nm in FIG. 10) was subtracted from the measured value at that time point, a relationship between the amount of variation and elapsed time after the D2 processing was examined and expressed with -●-.

Furthermore, for comparison, the optical fiber after the D2 processing was left as it is in the atmosphere without being rewound around another bobbin and the relationship between the amount of variation of transmission loss and elapsed time after the D2 processing was examined in that case, too. The result was expressed with -×-.

As is apparent from FIG. 12, it is appreciated that with the optical fiber manufactured according to the method in the example, free D2 molecules showing absorption loss in the vicinity of wavelength 1420 nm escaped in a shorter time than the optical fiber manufactured according to the method in the comparative example.

As is apparent from the above described explanation, when an attempt is made to manufacture an optical fiber whose hydrogen secular variation loss is reduced due to D2processing, this object can be achieved without leaving the fiber as it is for a long time after the D2 processing as in the case of the conventional art. This is the effect brought about by the present invention by cutting, splitting and rewinding the fiber while applying tensile tension immediately after the D2 processing.

Therefore, according to the method of the present invention, it is possible to produce an optical fiber which does not increase transmission loss in a short time and eliminate the need for a step of leaving the fiber as it is for a long time, and thereby eliminate the need for retaining many bobbins for rewinding the cut/split optical fibers for a long time, which will greatly contribute to practical use of D2 processing. 

1-10. (canceled)
 11. A manufacturing method of an optical fiber having a mode field diameter of 8.0 to 11.0 μm at a wavelength of 1310 nm, an average transmission loss at a wavelength of 1383 nm less than an average transmission loss at a wavelength of 1310 nm, and a dispersion of +2 to +8 ps/nm/km at the wavelength of 1383 nm, comprising the steps of drawing the optical fiber from an optical fiber preform, applying coating resins on said optical fiber, and exposing said optical fiber to a deuterium containing atmosphere.
 12. The manufacturing method of an optical fiber according to claim 11, wherein the optical fiber has a dispersion of +4 to +7 ps/nm/km at a wavelength of 1383 nm.
 13. The manufacturing method of an optical fiber according to claim 11, wherein said step of exposing is performed by exposing the optical fiber to the deuterium containing atmosphere under an ordinary pressure at an ordinary temperature.
 14. The manufacturing method of an optical fiber according to claim 13, wherein the exposing time in said step of exposing is 24 hours at longest.
 15. The manufacturing method of an optical fiber according to claim 11, wherein an increase in transmission loss at the wavelength of 1383 nm after hydrogen ageing is 0.04 dB/km or less.
 16. The manufacturing method of an optical fiber according to claim 11, wherein an increase in transmission loss at the wavelength of 1383 nm after hydrogen ageing is 0.01 dB/km or less.
 17. A manufacturing method of an optical fiber, including an exposing step of exposing the optical fiber after drawing to a deuterium containing atmosphere, wherein a difference between average transmission losses respectively at the wavelengths of 1385 nm and 1420 nm before said exposing step becomes different from a difference between average transmission losses respectively at the wavelengths of 1385 nm and 1420 nm after said exposing step, by 0.01 dB/km or more at least one time.
 18. The manufacturing method of an optical fiber according to claim 17, wherein a time interval from the time point at which said deuterium processing is started to the time point at which said transmission loss is measured is 48 hours or more at 25° C.
 19. The manufacturing method of an optical fiber according to claim 17, wherein the length of the optical fiber is 10 km or more and a cable cutoff wavelength at a length of 22 m of 1300 nm or less.
 20. A manufacturing method of an optical fiber, comprising the steps of drawing the optical fiber from an optical fiber preform, winding said optical fiber around a bobbin, and then immediately exposing said optical fiber to a deuterium containing atmosphere, wherein said optical fiber is rewound around another bobbin while applying tensile tension, before said deuterium is completely degassed from said optical fiber.
 21. The manufacturing method of an optical fiber according to claim 20, wherein said tensile tension corresponds to 0.5% to 2% in tensile strain of the optical fiber.
 22. The manufacturing method of an optical fiber according to claim 20, wherein said optical fiber is cut and divided into predetermined lengths in the longitudinal direction when said optical fiber is rewound. 